Contemporary Materials II−1 (2011)
Contemporary Materials II−1 (2011) Page 45 of 50
UDK 539.074.5:548.19
doi:10.5767/anurs.cmat.110201.en.045M
ULTRATHIN COATINGS OF ELECTRODES AND INFLUENCE OF PHONONS ON AN INCREASE OF CONDUCTIVITY OF LI-ION BATTERIES
D. Lj. Mirjanić1,*, J. P. Šetrajčić1,2, S. S. Pelemiš3, S. Armaković2
1 The Academy of Sciences and Arts of the Republic of Srpska, 78000 Banja Luka, Bana Lazarevića st. 1, Republic of Srpska, B&H
Abstract
This paper present the results of research of behaviour of phonon sub-system in ultrathin coatings that are applied on electrodes in Li-ion batteries and that increase the efficiency of ion transport. Using the method of Green functions it was demonstrated that in ultrathin films, increased mechanical oscillating of crystalline lattice and forming of standing waves occur, while, thermal capacitiveness and conduction of the overall coating decreases. With its increased oscillating, phonons release the ions captured on and within electrodes, and influence the increase of efficiency of ion conductivity.
Keywords: ion conductivity, Li-ion batteries, ultrathin films, phonons, heat capacity.
References
[2] P. L. Taberna, S. Mitra, P. Poizot, P. Simon & J. M. Tarascon, High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications, Nature Materials 5 (2006) 567–573.
[3] S. Pejovnik, R. Dominko, M. Bele, M. Gaberscek and J. Jamnik, Journal of Power Sources, Vol. 184, Issue 2, 593-597 (2008).
[4] J. Hong, Ch. Wang, U. Kasavajjula, Kinetic behavior of LiFeMgPO4 cathode material for Li-ion batteries, Journal of Power Sources 162 (2006) 1289 –1296.
[5] Yoon Seok Jung, Andrew S. Cavanagh,b Anne C. Dillon, Markus D. Groner, Steven M. George, and Se-Hee Leea, Enhanced Stability of LiCoO2 Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition, Journal of The Electrochemical Society, 157, 1, A75-A81,
[7] B. S. Tošić, J. P. Šetrajčić, D. Lj. Mirjanić, Z.V. Bundalo, Physica A vol. 184, 354-366 (1992).
[8] S. G. Davison and M. Steslicka: Basic Theory of Surface States, Clarendon, Oxford (1996).
[11] V.M. Golovach, G.G. Zegrya, A.M. Makhanets, I.V. Pronishin, N.V. Tkach, Semiconductors, vol.33/5, 564-568 (1999).
[12] J.M.Wesselinowa, Phys.Stat.Sol. (b), vol. 223, 737 (2001).
[13] J.M.Wesselinowa, Phys.Stat.Sol. (b), vol. 229, 1329 (2002).
[14] B.S. Tošić: Statisticka fizika, PMF, Novi Sad (1978).